C3H6FNO2
APtclcactv10301609273D 0   0.00000     0.00000
 
 13 12  0  0  1  0  0  0  0  0999 V2000
    1.2129    1.2367    0.4696 N   0  0  0  0  0  0  0  0  0  0  0  0
    0.6012   -0.0279    0.0401 C   0  0  2  0  0  0  0  0  0  0  0  0
    0.9882   -1.1395    1.0176 C   0  0  0  0  0  0  0  0  0  0  0  0
    1.0567   -0.3546   -1.2416 F   0  0  0  0  0  0  0  0  0  0  0  0
   -0.8982    0.1216    0.0175 C   0  0  0  0  0  0  0  0  0  0  0  0
   -1.3964    1.2216    0.0585 O   0  0  0  0  0  0  0  0  0  0  0  0
   -1.6803   -0.9673   -0.0483 O   0  0  0  0  0  0  0  0  0  0  0  0
    2.2112    1.0905    0.4699 H   0  0  0  0  0  0  0  0  0  0  0  0
    1.0191    1.9129   -0.2537 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.6333   -0.8849    2.0163 H   0  0  0  0  0  0  0  0  0  0  0  0
    0.5342   -2.0779    0.6990 H   0  0  0  0  0  0  0  0  0  0  0  0
    2.0727   -1.2476    1.0340 H   0  0  0  0  0  0  0  0  0  0  0  0
   -2.6425   -0.8714   -0.0629 H   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  1  0  0  0  0
  2  4  1  0  0  0  0
  2  5  1  0  0  0  0
  5  6  2  0  0  0  0
  5  7  1  0  0  0  0
  1  8  1  0  0  0  0
  1  9  1  0  0  0  0
  3 10  1  0  0  0  0
  3 11  1  0  0  0  0
  3 12  1  0  0  0  0
  7 13  1  0  0  0  0
M  END
> <UNIQUE_SMILES>
C[C@@](N)(F)C(O)=O

> <USER_SUPPLIED_SMILES>
N[C@](C)(F)C(=O)O

$$$$