We study synchronization due to noise and/or coupling in dynamical systems with multiple time scales. The challenge of taming nonuniformly hyperbolic structures is faced with non-standard geometric singular perturbation theory. An application focus is on biochemical oscillation reactions, with potential scope for wave fronts under noise.

pH-dependent reaction kinetics

The 4-variable model under consideration includes substrate transformation, product outflow, and exchange with the environment. Reaction rates are strongly influenced by pH-values.  

Figure 1: Urea−urease reaction confined to lipid vesicles

Figure 2. Phase portraits for two model reduction schemes. Although the nullclines are identical, flow field and limit cycles are qualitatively different.

 

Publications

2024
Excluded volume induces buckling in optically driven colloidal rings Phys. Rev. Research, Vol.6, p. L012044, 2024 Eric Cereceda-López, Mattia Ostinato, Antonio Ortiz-Ambriz, Arthur Straube, Matteo Palassini, Pietro Tierno BibTeX
arXiv
DOI
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators
Memory effects in colloidal motion under confinement and driving J. Phys. A: Math. Theor., Vol.57, p. 295003, 2024 Arthur Straube, Felix Höfling BibTeX
DOI
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators
Photocatalytic magnetic microgyroscopes with activity-tunable precessional dynamics 2024 (under review) Dolachai Boniface, Arthur Straube, Pietro Tierno BibTeX
arXiv
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators
Synchronization and random attractors in reaction jump processes Journal of Dynamics and Differential Equations, 2024 Maximilian Engel, Guillermo Olicón-Méndez, Nathalie Wehlitz, Stefanie Winkelmann BibTeX
arXiv
DOI
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators
2023
Accurate reduced models for the pH oscillations in the urea-urease reaction confined to giant lipid vesicles The Journal of Physical Chemistry B, 127(13), pp. 2955-2967, 2023 (preprint available as ZIB-Report 22-21) Arthur Straube, Stefanie Winkelmann, Felix Höfling PDF (ZIB-Report)
BibTeX
arXiv
DOI
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators
2021
Stochastic pH oscillations in a model of the urea–urease reaction confined to lipid vesicles J. Phys. Chem. Lett., Vol.12, pp. 9888-9893, 2021 Arthur Straube, Stefanie Winkelmann, Christof Schütte, Felix Höfling BibTeX
DOI
Synchronization and Geometric Structures of Stochastic Biochemical Oscillators